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Glutathione belongs in the second category.

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Subsequent clinical cases revealed that -synuclein pathology is not only restricted to the soma but also extends to neurites which led to the coinage of the term Lewy neurites ( Under normal physiological conditions -synuclein exists mostly in an N acetylated membrane bound form which results in adoption of an -helical structure (Runfola et al., 2020)

Regenerates other antioxidants: Glutathione recycles vitamin C and vitamin E back to their active forms after they've neutralized free radicals so other antioxidants depend on adequate glutathione to keep working