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Peptides were eluted over a 2-h gradient of ACN (537%) in 0.1% FA at 400 nL/min while being injected into a TimsTOF Pro ion mobility mass spectrometer equipped with a Captive Spray nano electrospray source (Bruker Daltonics)

Both hormones are involved in adrenarche, and the increase in their concentration at the age of 6-8 years is probably of key importance in the development of social and cultural skills (267)

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