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According to Xiao et al (63), iron ions accelerate AS by generating free radicals, which induce endothelial cell apoptosis and oxidize LDL, promoting macrophage uptake

In overweight/obese PCOS women with vitamin D deficiency, daily administration of 1,000 mg of calcium combined with 50,000 IU of vitamin D weekly for 8 weeks revealed that calcium supplementation, with or without additional vitamin D, resulted in significant diminutions in FBG, FINS, HOMA-IR, TG, and VLDL-C, along with a notable increase in the QUICKI (117)

doi: 10.1124/pr.117.015198

doi: 10.3390/jof8121275 198 TangX.WuJ.WuW.ZhangZ.ZhangW.ZhangQ.et al

The switch between these two states occurred relatively fast because we did not register any intermediate states or smooth shifts in biophysical parameters at different values of oxidative stress