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In contrast, thapsigargin induced both ER stress and calreticulin release in neuroblastoma and MEFs (139)

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In particular, the glyoxalase I-catalysed isomerization of hemithioacetals involves the sequential formation of -hemithioacetal, deprotonation to form the enediol intermediate and its enantioselective reprotonation 3 , leading to the formation of enantiopure -hydroxythioesters 4,5,6 (Fig